硅灰石、透辉石在陶瓷中的基本反应和作用   总被引：5，自引：0，他引：5       下载免费PDF全文

戴长禄  张振禹 《地质科学》1990,(4):359-366

本文以硅灰石和高岭石、透辉石和高岭石为端元组分,推导了二元假相图。根据这两个假相图,提出了四个基本固相反应。用这些基本反应以及硅灰石、透辉石的矿物学性质,说明了它们对陶瓷坯体工艺性能的作用。  相似文献   

新疆黄山杂岩体矿物学特征及其意义   总被引：1，自引：0，他引：1  

钟应先 《矿物岩石》1991,11(1):14-23

黄山杂岩体造岩矿物有橄榄石、斜方辉石、单斜辉石、斜长石、角闪石和黑云母。其中斜方辉石的多色性不是由Fe~(2+)引起,而是由Ti~(4+)引起。单斜辉石结晶后常与岩浆继续发生化学反应,形成一种岩浆岩结构——角闪反应补丁结构。橄榄石中镍含量的亏损程度反映杂岩体曾经历过硫化物熔离作用。单斜辉石Si,Al~Ⅳ,Ti的变化表明杂岩体属于拉斑玄武岩系列。超镁铁岩中K,Ba,Th,Hf等元素反常的地球化学行为是由该岩石中黑云母矿物引起。  相似文献   

冀东陆壳结构的岩石学模型   总被引：7，自引：4，他引：7       下载免费PDF全文

吴宗絮  郭才华 《地震地质》1991,13(4):369-376

冀东地区的古老变质岩系是一个出露的大陆地壳断面。根据变质岩系的变质相、亚相的研究和地质温压计计算的结果推定的深度,并结合地球物理测深资料,以及笔者测定和前人的岩石高压下波速实验资料提出了本区大陆地壳结构的岩石学模型。下地壳由麻粒岩相岩石组成,上部为角闪石麻粒岩亚相的中性成分的麻粒岩,下部为辉石麻粒岩亚相的基性成分的麻粒岩构成,底部夹有透镜状蛇纹石化橄榄岩以及紫苏花岗岩。中地壳主要由高角闪岩相的中性-中酸性成分的片麻岩、片岩构成,顶部为低角闪岩相的片麻岩、片岩,广泛发育英云闪长岩和花岗闪长岩岩体,含隙间高温流体相(fluid phase),形成高导-低速层。上地壳主要为绿片岩相(部分低角闪岩相)的板岩、千枚岩、片岩、变粒岩以及花岗岩组成,顶部为沉积盖层  相似文献   

大青山造山带中基底再造杂岩的特征及其指示意义   总被引：4，自引：0，他引：4  

刘喜山 《岩石学报》1994,(4)

大青山造山带中基底再造杂岩主要由高温韧性剪切变形变质作用的糜棱片麻岩类、部分重烙作用形成的混合岩化糜棱片麻岩类及太古宙地壳残块三部分组成。进一步研究表明该基底再造条岩不仅可以作为一个特定的构造岩性单元，属于造山带根部地壳的一部分，而且其中前两部分既不属于太古富变质上壳岩和侵入岩系，也不属于早元古代变质上亮岩，而是早元古代造山带演化过程中，变形变质作用和部分重熔作用对太古宙基底综合改造作用的产物。基底再造杂岩的研究为进一步探讨前寒武纪克拉通内硅铝壳造山作用的性质、规模和成因机制提供了极为重要的地质证据和信息。  相似文献   

Tertiary extension of continental crust and uplift of Psiloritis metamorphic core complex in the central part of the Hellenic Arc (Crete,Greece)     

Adamantios Kilias  Charalampos Fassoulas  Demosthenis Mountrakis 《International Journal of Earth Sciences》1994,83(2):417-430

Kinematic analysis of the deformation in central Crete suggests that the structural evolution and exhumation of the high pressure/low temperature (HP/LT) rocks outcropping at the Mount Psiloritis metamorphic core complex are associated with a regional, Miocene, north-south extension and thinning of the continental crust. This tectonic regime developed under bulk coaxial strain conditions, with ductile deformation in the lower and brittle deformation in the upper crust, and followed, on the decompressional path, a north-south compression associated with a HP/LT metamorphism in the lower crust. This compressional event took place during Oligocene—Early Miocene and led to overthickening of the accretionary wedge in the Hellenic Arc. An east-west directed compression accompanied, in the final stages, the Miocene north-south extension of the continental crust.  相似文献   

Geothermobarometry of mafic granulites and metapelite from the Palghat Gap, South India: petrological evidence for isothermal uplift and rapid cooling   总被引：1，自引：0，他引：1  

C. R. RAVINDRA. KUMAR  T. CHACKO 《Journal of Metamorphic Geology》1994,12(4):479-492

The Palghat Gap region is located near the centre of the large southern Indian granulite terrane. at the northern edge of the Kodaikanal charnockite massif. The dominant rock types in the region are hornblende-biotite ± orthopyroxene gneisses and charnockites along with minor amounts of intercalated mafic granulite, metapelite and calc-silicate. The P-T estimates from garnetiferous mafic granulites and metapelite samples are generally in the range 9-10 kbar and 800-900 C using both conventional thermobarometric methods and the TWEEQU thermobarometry program. These P-T estimates, which should be taken as minimum values, are among the highest yet reported for South Indian and Sri Lankan granulites. The occurrence of orthopyroxene + plagioclase symplectites around embayed garnet grains in the mafic granulites and cordierite rims around garnet grains in metapelite suggest an isothermal decompression-type path. Similarly, a core-rim P-T trajectory indicates c. 3 and 7 kbar decompression at high temperature in the mafic granulites and metapelite, respectively. In both rock types, the key to the determination of the retrograde P-T path was the recognition of small amounts of second generation plagioclase with a more anorthitic composition than the matrix plagioclase. The preservation of high garnet-pyroxene temperatures in the mafic granulites (despite small garnet grain size) suggests rapid cooling of the terrane. Calculated minimum cooling rates range from 8 to 80 C Ma^-1. Such cooling rates are more rapid than those associated with normal isostatic processes and suggest that the terrane was tectonically exhumed at high temperature.  相似文献   

热液成矿作用的一般动力学方程   总被引：3，自引：1，他引：3       下载免费PDF全文

鲍征宇  唐促华 《地球科学》1994,19(3):313-319

分析了热液成矿作用的基本特点和研究现状，推导出热液成矿作用动力学体系的一般方程，并着重讨论了方程中表征热液与围岩之间化学反应的速率项，除目前一般采用动力学实验实测反应速率常数外，作者根据局域平衡原理，认为成矿作用可视为体系内各点随着温度和压力的变化不断重建平衡的过程，可用温度和压力变化时成矿反应的平衡常数的变化速度表征成矿反应的动力学行为，成矿化学反应的速率还可用主要成矿物质的溶解的变化率来表征。  相似文献   

Prediction of the abiotic degradability of organic compounds in the troposphere     

Hans Güsten  Leo Klasinc  Dubravko Marić 《Journal of Atmospheric Chemistry》1984,2(1):83-93

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.  相似文献   

对胶南群的异议     

纪壮义  赵环金 《地震地质》1995,17(1):79-85

对苏北～胶南一带胶南群的变质岩系进行研究，其边界特征、横向不连续性、岩石类型及相互关系、同位素年龄等资料表明，胶南群不具有单一地层单元的含义，而是挟于五莲－荣成断裂与海州－泗阳断裂之间的构造岩石组合体，它由上壳岩类和深源岩类组成，前者包括了３个构造位。其形成可能与边界深大断裂的开合作用有关  相似文献   

Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems     

Eric A. Betterton  Darcy J. Anderson 《Journal of Atmospheric Chemistry》2001,40(2):171-189

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.  相似文献